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[{"key": "dc.contributor.author", "value": "Tero, Tiia-Riikka", "language": null, "element": "contributor", "qualifier": "author", "schema": "dc"}, {"key": "dc.date.accessioned", "value": "2025-01-17T07:01:46Z", "language": null, "element": "date", "qualifier": "accessioned", "schema": "dc"}, {"key": "dc.date.available", "value": "2025-01-17T07:01:46Z", "language": null, "element": "date", "qualifier": "available", "schema": "dc"}, {"key": "dc.date.issued", "value": "2015", "language": null, "element": "date", "qualifier": "issued", "schema": "dc"}, {"key": "dc.identifier.isbn", "value": "978-951-39-6109-1", "language": null, "element": "identifier", "qualifier": "isbn", "schema": "dc"}, {"key": "dc.identifier.uri", "value": "https://jyx.jyu.fi/handle/123456789/99573", "language": null, "element": "identifier", "qualifier": "uri", "schema": "dc"}, {"key": "dc.description.abstract", "value": "The synthesis and characterization of new tetramethoxy resorcinarene \r\nderivatives are described. The new compounds are obtained and characterized \r\nin solution and solid state, along with halogen bonded networks. In the coming \r\npages the structural and photophysical properties of newly synthesized \r\ntetramethodxy resorcinarene derivatives will be presented. \r\nA previously unknown derivative of the tetramethoxy resorcinarene \r\nplatform, methyl tetramethoxy resorcinarene, was synthesized completing the \r\nfamily of tetramethoxy resorcinarenes. Methyl C1- and ethyl C2-tetramethoxy \r\nresorcinarenes were used as platforms for the syntheses of five different \r\npyridine and benzyl functionalized resorcinarene tetrapodands, and for the \r\ncrown-ether bridged benzofuran resorcinarene derivative. The structural \r\nproperties of these compounds were studied in solution by NMR spectroscopy \r\nand in the solid state by X-ray crystallography. Only one carbon difference in \r\nthe lower rim alkyl groups, methyl vs. ethyl, was observed to affect the \r\ndynamic behavior of resorcinarene podands in solution. In the solid state, \r\nmethyl tetramethoxy resorcinarene obeyed compact \u201cbrick\u201d-like packing made \r\npossible by the small methyl group at the lower rim. \r\nThe pyridine functionalized resorcinarene podands were used in the \r\nconstruction of solid state halogen bonded architectures with halobenzene \r\nlinkers. The structural characteristics of the resorcinarene scaffold and the \r\npodand arms allowed the formation of multidimensional networks showing \r\npotentially porous properties. In solution, although no formation of larger \r\nassemblies were observed, halogen bonding between resorcinarenes and the \r\nlinkers was confirmed; and the observed interactions were supported by \r\ncomputational methods. \r\nIn the synthesis of crown bridged resorcinarenes, a side product was \r\nisolated that contained an unusual benzofuran fused macrocyclic structure. The \r\nmodified macrocycle had characteristic fluorescence properties and the study \r\nshowed that emission/excitation matrix spectroscopy is a valid tool for \r\nstructure analysis in solution.", "language": "en", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted by Miia Hakanen (mihakane@jyu.fi) on 2025-01-17T07:01:46Z\r\nNo. of bitstreams: 0", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Made available in DSpace on 2025-01-17T07:01:46Z (GMT). No. of bitstreams: 0\r\n Previous issue date: 2015", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.format.extent", "value": "61, [47] sivua", "language": null, "element": "format", "qualifier": "extent", "schema": "dc"}, {"key": "dc.language.iso", "value": "eng", "language": null, "element": "language", "qualifier": "iso", "schema": "dc"}, {"key": "dc.publisher", "value": "University of Jyv\u00e4skyl\u00e4", "language": null, "element": "publisher", "qualifier": null, "schema": "dc"}, {"key": "dc.relation.ispartofseries", "value": "Research report / Department of Chemistry, University of Jyv\u00e4skyl\u00e4", "language": null, "element": "relation", "qualifier": "ispartofseries", "schema": "dc"}, {"key": "dc.rights", "value": "In Copyright", "language": null, "element": "rights", "qualifier": null, "schema": "dc"}, {"key": "dc.title", "value": "Tetramethoxy resorcinarens as platforms for fluorescent and halogen bonding systems", "language": null, "element": "title", "qualifier": null, "schema": "dc"}, {"key": "dc.type", "value": "doctoral thesis", "language": null, "element": "type", "qualifier": null, "schema": "dc"}, {"key": "dc.identifier.urn", "value": "URN:ISBN:978-951-39-6109-1", "language": null, "element": "identifier", "qualifier": "urn", "schema": "dc"}, {"key": "dc.type.dcmitype", "value": "Text", "language": "en", "element": "type", "qualifier": "dcmitype", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Doctoral dissertation", "language": "en", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "V\u00e4it\u00f6skirja", "language": "fi", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Matemaattis-luonnontieteellinen tiedekunta", "language": "fi", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Faculty of Mathematics and Science", "language": "en", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Kemian laitos", "language": "fi", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Department of Chemistry", "language": "en", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "University of Jyv\u00e4skyl\u00e4", "language": "en", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "Jyv\u00e4skyl\u00e4n yliopisto", "language": "fi", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.type.coar", "value": "http://purl.org/coar/resource_type/c_db06", "language": null, "element": "type", "qualifier": "coar", "schema": "dc"}, {"key": "dc.relation.issn", "value": "0357-346X", "language": null, "element": "relation", "qualifier": "issn", "schema": "dc"}, {"key": "dc.relation.numberinseries", "value": "181", "language": null, "element": "relation", "qualifier": "numberinseries", "schema": "dc"}, {"key": "dc.type.version", "value": "publishedVersion", "language": null, "element": "type", "qualifier": "version", "schema": "dc"}, {"key": "dc.rights.copyright", "value": "\u00a9 2015 University of Jyv\u00e4skyl\u00e4", "language": null, "element": "rights", "qualifier": "copyright", "schema": "dc"}, {"key": "dc.rights.accesslevel", "value": "openAccess", "language": null, "element": "rights", "qualifier": "accesslevel", "schema": "dc"}, {"key": "dc.type.publication", "value": "doctoralThesis", "language": null, "element": "type", "qualifier": "publication", "schema": "dc"}, {"key": "dc.subject.yso", "value": "NMR-spektroskopia", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "spektroskopia", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "laskennallinen kemia", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "kemialliset sidokset", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "kemiallinen synteesi", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "jyx.subject.uri", "value": "http://www.yso.fi/onto/yso/p26254", "language": null, "element": "subject", "qualifier": "uri", "schema": "jyx"}, {"key": "jyx.subject.uri", "value": "http://www.yso.fi/onto/yso/p10176", "language": null, "element": "subject", "qualifier": "uri", "schema": "jyx"}, {"key": "jyx.subject.uri", "value": "http://www.yso.fi/onto/yso/p23053", "language": null, "element": "subject", "qualifier": "uri", "schema": "jyx"}, {"key": "jyx.subject.uri", "value": "http://www.yso.fi/onto/yso/p10130", "language": null, "element": "subject", "qualifier": "uri", "schema": "jyx"}, {"key": "jyx.subject.uri", "value": "http://www.yso.fi/onto/yso/p8468", "language": null, "element": "subject", "qualifier": "uri", "schema": "jyx"}, {"key": "dc.rights.url", "value": "https://rightsstatements.org/page/InC/1.0/", "language": null, "element": "rights", "qualifier": "url", "schema": "dc"}]
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