Synthesis of cyanoethyl- and carbamoylethylcellulose

The tentative plan of the research described in this study was to clarify a possibility to use cyanoethylation of cellulose as an intermediate step in the synthesis of carboxyethylcellulose. During the work it turned out that compared to cyanoethylation carbamoylethylation of cellulose provides a be...

Täydet tiedot

Bibliografiset tiedot
Päätekijä: Roulamo, Anneli
Muut tekijät: Matemaattis-luonnontieteellinen tiedekunta, Faculty of Sciences, Kemian laitos, Department of Chemistry, Jyväskylän yliopisto, University of Jyväskylä
Aineistotyyppi: Pro gradu
Kieli:eng
Julkaistu: 2003
Aiheet:
Linkit: https://jyx.jyu.fi/handle/123456789/88335
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author Roulamo, Anneli
author2 Matemaattis-luonnontieteellinen tiedekunta Faculty of Sciences Kemian laitos Department of Chemistry Jyväskylän yliopisto University of Jyväskylä
author_facet Roulamo, Anneli Matemaattis-luonnontieteellinen tiedekunta Faculty of Sciences Kemian laitos Department of Chemistry Jyväskylän yliopisto University of Jyväskylä Roulamo, Anneli Matemaattis-luonnontieteellinen tiedekunta Faculty of Sciences Kemian laitos Department of Chemistry Jyväskylän yliopisto University of Jyväskylä
author_sort Roulamo, Anneli
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description The tentative plan of the research described in this study was to clarify a possibility to use cyanoethylation of cellulose as an intermediate step in the synthesis of carboxyethylcellulose. During the work it turned out that compared to cyanoethylation carbamoylethylation of cellulose provides a better intermediate for the conversation for the final product. Especially, the effect of common organic solvents on the degree of substitution was studied. Guidelines for synthesis of water-soluble carbamoylethyl-carboxyethyl cellulose mixed ether in xylene are described. Characterisation of the products was carried out by means of NMR spectroscopy, FTIR spectroscipy, and the analysis of nitrogen (Kjeldahl) and sodium carboxylate content. The literature based introduction gives insight into the derivatisation of cellulose by the Michael addition, and a description of the product properties.
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During the work it turned out that compared to cyanoethylation carbamoylethylation of cellulose provides a better intermediate for the conversation for the final product. Especially, the effect of common organic solvents on the degree of substitution was studied. Guidelines for synthesis of water-soluble carbamoylethyl-carboxyethyl cellulose mixed ether in xylene are described. 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spellingShingle Roulamo, Anneli Synthesis of cyanoethyl- and carbamoylethylcellulose liuottimet Soveltava kemia Applied Chemistry 4036 orgaaninen kemia spektroskopia selluloosa NMR-spektroskopia organic chemistry spectroscopy cellulose NMR spectroscopy
title Synthesis of cyanoethyl- and carbamoylethylcellulose
title_full Synthesis of cyanoethyl- and carbamoylethylcellulose
title_fullStr Synthesis of cyanoethyl- and carbamoylethylcellulose Synthesis of cyanoethyl- and carbamoylethylcellulose
title_full_unstemmed Synthesis of cyanoethyl- and carbamoylethylcellulose Synthesis of cyanoethyl- and carbamoylethylcellulose
title_short Synthesis of cyanoethyl- and carbamoylethylcellulose
title_sort synthesis of cyanoethyl and carbamoylethylcellulose
title_txtP Synthesis of cyanoethyl- and carbamoylethylcellulose
topic liuottimet Soveltava kemia Applied Chemistry 4036 orgaaninen kemia spektroskopia selluloosa NMR-spektroskopia organic chemistry spectroscopy cellulose NMR spectroscopy
topic_facet 4036 Applied Chemistry NMR spectroscopy NMR-spektroskopia Soveltava kemia cellulose liuottimet orgaaninen kemia organic chemistry selluloosa spectroscopy spektroskopia
url https://jyx.jyu.fi/handle/123456789/88335 http://www.urn.fi/URN:NBN:fi:jyu-202307104462
work_keys_str_mv AT roulamoanneli synthesisofcyanoethylandcarbamoylethylcellulose