Synthesis of photocleavable protected terminal alkynes for self-assembled monolayers and single molecule electronics

The theoretical part of the thesis introduces self-assembled monolayers, their applications in a view of organic electronics and usage of photocleavable protection groups. Alkanethiol SAMs on gold surface and their surface modifications in a different approach are focused. Theoretical work also cont...

Full description

Bibliographic Details
Main Author: Peltonen, Petra
Other Authors: Matemaattis-luonnontieteellinen tiedekunta, Faculty of Sciences, Kemian laitos, Department of Chemistry, Jyväskylän yliopisto, University of Jyväskylä
Format: Master's thesis
Language:eng
Published: 2021
Subjects:
Online Access: https://jyx.jyu.fi/handle/123456789/77292
_version_ 1828193065322414080
author Peltonen, Petra
author2 Matemaattis-luonnontieteellinen tiedekunta Faculty of Sciences Kemian laitos Department of Chemistry Jyväskylän yliopisto University of Jyväskylä
author_facet Peltonen, Petra Matemaattis-luonnontieteellinen tiedekunta Faculty of Sciences Kemian laitos Department of Chemistry Jyväskylän yliopisto University of Jyväskylä Peltonen, Petra Matemaattis-luonnontieteellinen tiedekunta Faculty of Sciences Kemian laitos Department of Chemistry Jyväskylän yliopisto University of Jyväskylä
author_sort Peltonen, Petra
datasource_str_mv jyx
description The theoretical part of the thesis introduces self-assembled monolayers, their applications in a view of organic electronics and usage of photocleavable protection groups. Alkanethiol SAMs on gold surface and their surface modifications in a different approach are focused. Theoretical work also contains some information about traditional protection groups and synthesis which are related to the experimental part. The aim of experimental part was to synthesize a photocleavable protected arylpropiolic acid with an alkanethiol anchoring group and apply it on a gold surface. Prepared monolayer could be used for surface modification and release the terminal alkyne by light activation for further reactions. If experiment could succeed, there is a potential to create a single molecule electronics. As a result, the formation of self-assembled monolayer could not prove via used characterization methods.
first_indexed 2021-08-06T20:00:32Z
format Pro gradu
fullrecord [{"key": "dc.contributor.advisor", "value": "Lahtinen, Tanja", "language": "", "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.author", "value": "Peltonen, Petra", "language": "", "element": "contributor", "qualifier": "author", "schema": "dc"}, {"key": "dc.date.accessioned", "value": "2021-08-06T06:02:18Z", "language": null, "element": "date", "qualifier": "accessioned", "schema": "dc"}, {"key": "dc.date.available", "value": "2021-08-06T06:02:18Z", "language": null, "element": "date", "qualifier": "available", "schema": "dc"}, {"key": "dc.date.issued", "value": "2021", "language": "", "element": "date", "qualifier": "issued", "schema": "dc"}, {"key": "dc.identifier.uri", "value": "https://jyx.jyu.fi/handle/123456789/77292", "language": null, "element": "identifier", "qualifier": "uri", "schema": "dc"}, {"key": "dc.description.abstract", "value": "The theoretical part of the thesis introduces self-assembled monolayers, their applications in a view of organic electronics and usage of photocleavable protection groups. Alkanethiol SAMs on gold surface and their surface modifications in a different approach are focused. Theoretical work also contains some information about traditional protection groups and synthesis which are related to the experimental part. \nThe aim of experimental part was to synthesize a photocleavable protected arylpropiolic acid with an alkanethiol anchoring group and apply it on a gold surface. Prepared monolayer could be used for surface modification and release the terminal alkyne by light activation for further reactions. If experiment could succeed, there is a potential to create a single molecule electronics. As a result, the formation of self-assembled monolayer could not prove via used characterization methods.", "language": "en", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted by Paivi Vuorio (paelvuor@jyu.fi) on 2021-08-06T06:02:18Z\nNo. of bitstreams: 0", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Made available in DSpace on 2021-08-06T06:02:18Z (GMT). No. of bitstreams: 0\n Previous issue date: 2021", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.format.extent", "value": "98", "language": "", "element": "format", "qualifier": "extent", "schema": "dc"}, {"key": "dc.format.mimetype", "value": "application/pdf", "language": null, "element": "format", "qualifier": "mimetype", "schema": "dc"}, {"key": "dc.language.iso", "value": "eng", "language": null, "element": "language", "qualifier": "iso", "schema": "dc"}, {"key": "dc.rights", "value": "In Copyright", "language": "en", "element": "rights", "qualifier": null, "schema": "dc"}, {"key": "dc.subject.other", "value": "self-assebled monolayer", "language": "", "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "photocleavable protection", "language": "", "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.title", "value": "Synthesis of photocleavable protected terminal alkynes for self-assembled monolayers and single molecule electronics", "language": "", "element": "title", "qualifier": null, "schema": "dc"}, {"key": "dc.type", "value": "master thesis", "language": null, "element": "type", "qualifier": null, "schema": "dc"}, {"key": "dc.identifier.urn", "value": "URN:NBN:fi:jyu-202108064459", "language": "", "element": "identifier", "qualifier": "urn", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Pro gradu -tutkielma", "language": "fi", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Master\u2019s thesis", "language": "en", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Matemaattis-luonnontieteellinen tiedekunta", "language": "fi", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Faculty of Sciences", "language": "en", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Kemian laitos", "language": "fi", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Department of Chemistry", "language": "en", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "Jyv\u00e4skyl\u00e4n yliopisto", "language": "fi", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "University of Jyv\u00e4skyl\u00e4", "language": "en", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Nanotiede", "language": "fi", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Nanoscience", "language": "en", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "yvv.contractresearch.funding", "value": "0", "language": "", "element": "contractresearch", "qualifier": "funding", "schema": "yvv"}, {"key": "dc.type.coar", "value": "http://purl.org/coar/resource_type/c_bdcc", "language": null, "element": "type", "qualifier": "coar", "schema": "dc"}, {"key": "dc.rights.accesslevel", "value": "restrictedAccess", "language": null, "element": "rights", "qualifier": "accesslevel", "schema": "dc"}, {"key": "dc.type.publication", "value": "masterThesis", "language": null, "element": "type", "qualifier": "publication", "schema": "dc"}, {"key": "dc.subject.oppiainekoodi", "value": "4033", "language": "", "element": "subject", "qualifier": "oppiainekoodi", "schema": "dc"}, {"key": "dc.subject.yso", "value": "orgaaninen kemia", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "kemia", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "kulta", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "organic chemistry", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "chemistry", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "gold", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.format.content", "value": "fulltext", "language": null, "element": "format", "qualifier": "content", "schema": "dc"}, {"key": "dc.rights.url", "value": "https://rightsstatements.org/page/InC/1.0/", "language": null, "element": "rights", "qualifier": "url", "schema": "dc"}, {"key": "dc.rights.accessrights", "value": "Tekij\u00e4 ei ole antanut lupaa avoimeen julkaisuun, joten aineisto on luettavissa vain Jyv\u00e4skyl\u00e4n yliopiston kirjaston <a href=\"https://kirjasto.jyu.fi/kokoelmat/arkistotyoasema\">arkistoty\u00f6asemalta</a>.", "language": "fi", "element": "rights", "qualifier": "accessrights", "schema": "dc"}, {"key": "dc.rights.accessrights", "value": "<br><br>The author has not given permission to make the work publicly available electronically. Therefore the material can be read only at the archival <a href=\"https://kirjasto.jyu.fi/collections/archival-workstation\">workstation</a> at Jyv\u00e4skyl\u00e4 University Library reserved for the use of archival materials.", "language": "en", "element": "rights", "qualifier": "accessrights", "schema": "dc"}, {"key": "dc.type.okm", "value": "G2", "language": null, "element": "type", "qualifier": "okm", "schema": "dc"}]
id jyx.123456789_77292
language eng
last_indexed 2025-03-31T20:02:29Z
main_date 2021-01-01T00:00:00Z
main_date_str 2021
publishDate 2021
record_format qdc
source_str_mv jyx
spellingShingle Peltonen, Petra Synthesis of photocleavable protected terminal alkynes for self-assembled monolayers and single molecule electronics self-assebled monolayer photocleavable protection Nanotiede Nanoscience 4033 orgaaninen kemia kemia kulta organic chemistry chemistry gold
title Synthesis of photocleavable protected terminal alkynes for self-assembled monolayers and single molecule electronics
title_full Synthesis of photocleavable protected terminal alkynes for self-assembled monolayers and single molecule electronics
title_fullStr Synthesis of photocleavable protected terminal alkynes for self-assembled monolayers and single molecule electronics Synthesis of photocleavable protected terminal alkynes for self-assembled monolayers and single molecule electronics
title_full_unstemmed Synthesis of photocleavable protected terminal alkynes for self-assembled monolayers and single molecule electronics Synthesis of photocleavable protected terminal alkynes for self-assembled monolayers and single molecule electronics
title_short Synthesis of photocleavable protected terminal alkynes for self-assembled monolayers and single molecule electronics
title_sort synthesis of photocleavable protected terminal alkynes for self assembled monolayers and single molecule electronics
title_txtP Synthesis of photocleavable protected terminal alkynes for self-assembled monolayers and single molecule electronics
topic self-assebled monolayer photocleavable protection Nanotiede Nanoscience 4033 orgaaninen kemia kemia kulta organic chemistry chemistry gold
topic_facet 4033 Nanoscience Nanotiede chemistry gold kemia kulta orgaaninen kemia organic chemistry photocleavable protection self-assebled monolayer
url https://jyx.jyu.fi/handle/123456789/77292 http://www.urn.fi/URN:NBN:fi:jyu-202108064459
work_keys_str_mv AT peltonenpetra synthesisofphotocleavableprotectedterminalalkynesforselfassembledmonolayersandsing