The role of oxidation treatments before and after CVD synthesis of graphene on copper catalytic surface

Graphene is a sheet of honeycomb bonded carbon, that is only one atom thick. Aside from its remarkable strength, graphene has great conducting and photochemical prop erties. Due to its unique properties, it can be used as viable option for rare metals in circuits and in new type of measuring compo...

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Main Author: Neuvonen, Santeri
Other Authors: Matemaattis-luonnontieteellinen tiedekunta, Faculty of Sciences, Kemian laitos, Department of Chemistry, Jyväskylän yliopisto, University of Jyväskylä
Format: Bachelor's thesis
Language:eng
Published: 2021
Subjects:
Online Access: https://jyx.jyu.fi/handle/123456789/76987
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author Neuvonen, Santeri
author2 Matemaattis-luonnontieteellinen tiedekunta Faculty of Sciences Kemian laitos Department of Chemistry Jyväskylän yliopisto University of Jyväskylä
author_facet Neuvonen, Santeri Matemaattis-luonnontieteellinen tiedekunta Faculty of Sciences Kemian laitos Department of Chemistry Jyväskylän yliopisto University of Jyväskylä Neuvonen, Santeri Matemaattis-luonnontieteellinen tiedekunta Faculty of Sciences Kemian laitos Department of Chemistry Jyväskylän yliopisto University of Jyväskylä
author_sort Neuvonen, Santeri
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description Graphene is a sheet of honeycomb bonded carbon, that is only one atom thick. Aside from its remarkable strength, graphene has great conducting and photochemical prop erties. Due to its unique properties, it can be used as viable option for rare metals in circuits and in new type of measuring components. To express these properties at their best, graphene should be single crystal and as clean as possible. In this bachelor thesis, different treatment options for catalytic metal surface for graphene synthesis are studied in chemical vapor deposition growth. Different options to treat the catalytic metal layer were studied, such as changes in gas compositions in annealing process, electropolishing, plasma and UV-light treatment. All the processes effect the oxidation level of the surface. Different catalytic metals can also lead to higher quality graphene. Synthesised graphene can be cleaned from amorphous carbon by treating it with carbon dioxide or changing the carbon precursor for the chemical vapor deposition process. In the experimental part, the effects of higher concentration of hydrogen during synthesis was studied. Higher concentration of hydrogen led to lower nucleation density of graphene, but the catalytic copper surface was damaged in these processes. After synthesis, anneal ing under carbon dioxide flow was studied as a means of cleaning the surface. It was found to reduce amorphous carbon in the product but it increased the manifestation of double layers.
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Aside\r\nfrom its remarkable strength, graphene has great conducting and photochemical prop erties. Due to its unique properties, it can be used as viable option for rare metals in\r\ncircuits and in new type of measuring components. To express these properties at their\r\nbest, graphene should be single crystal and as clean as possible.\r\nIn this bachelor thesis, different treatment options for catalytic metal surface for graphene\r\nsynthesis are studied in chemical vapor deposition growth. Different options to treat the\r\ncatalytic metal layer were studied, such as changes in gas compositions in annealing\r\nprocess, electropolishing, plasma and UV-light treatment. All the processes effect the\r\noxidation level of the surface. Different catalytic metals can also lead to higher quality\r\ngraphene. 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spellingShingle Neuvonen, Santeri The role of oxidation treatments before and after CVD synthesis of graphene on copper catalytic surface Kemia Chemistry 4038 grafeeni ohutkalvot pintakäsittely hiilidioksidi hapetus nanorakenteet puhdistus kemiallinen synteesi kupari graphene thin films surface treatment carbon dioxide oxidation (active) nanostructures cleaning chemical synthesis copper
title The role of oxidation treatments before and after CVD synthesis of graphene on copper catalytic surface
title_full The role of oxidation treatments before and after CVD synthesis of graphene on copper catalytic surface
title_fullStr The role of oxidation treatments before and after CVD synthesis of graphene on copper catalytic surface The role of oxidation treatments before and after CVD synthesis of graphene on copper catalytic surface
title_full_unstemmed The role of oxidation treatments before and after CVD synthesis of graphene on copper catalytic surface The role of oxidation treatments before and after CVD synthesis of graphene on copper catalytic surface
title_short The role of oxidation treatments before and after CVD synthesis of graphene on copper catalytic surface
title_sort role of oxidation treatments before and after cvd synthesis of graphene on copper catalytic surface
title_txtP The role of oxidation treatments before and after CVD synthesis of graphene on copper catalytic surface
topic Kemia Chemistry 4038 grafeeni ohutkalvot pintakäsittely hiilidioksidi hapetus nanorakenteet puhdistus kemiallinen synteesi kupari graphene thin films surface treatment carbon dioxide oxidation (active) nanostructures cleaning chemical synthesis copper
topic_facet 4038 Chemistry Kemia carbon dioxide chemical synthesis cleaning copper grafeeni graphene hapetus hiilidioksidi kemiallinen synteesi kupari nanorakenteet nanostructures ohutkalvot oxidation (active) pintakäsittely puhdistus surface treatment thin films
url https://jyx.jyu.fi/handle/123456789/76987 http://www.urn.fi/URN:NBN:fi:jyu-202107054173
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