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[{"key": "dc.contributor.advisor", "value": "Lahtinen, Manu", "language": "", "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.advisor", "value": "Forsblom, Samu", "language": "", "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.author", "value": "Rumbin, Niko", "language": "", "element": "contributor", "qualifier": "author", "schema": "dc"}, {"key": "dc.date.accessioned", "value": "2020-06-22T11:37:15Z", "language": null, "element": "date", "qualifier": "accessioned", "schema": "dc"}, {"key": "dc.date.available", "value": "2020-06-22T11:37:15Z", "language": null, "element": "date", "qualifier": "available", "schema": "dc"}, {"key": "dc.date.issued", "value": "2020", "language": "", "element": "date", "qualifier": "issued", "schema": "dc"}, {"key": "dc.identifier.uri", "value": "https://jyx.jyu.fi/handle/123456789/70118", "language": null, "element": "identifier", "qualifier": "uri", "schema": "dc"}, {"key": "dc.description.abstract", "value": "T\u00e4ss\u00e4 Pro Gradu \u2013tutkielmassa k\u00e4sitell\u00e4\u00e4n kahta erityisesti supramolekulaarisen kemian\nalalla viime aikoina runsaasti tutkittua aihetta: koordinaatioh\u00e4kkej\u00e4 ja\nhalogeenisitoutumista. Koordinaatioh\u00e4kkien molekylaaristen rakenteiden monimuotoisuus\nja k\u00e4ytt\u00f6kelpoisuus erilaisissa sovelluksissa on tehnyt niist\u00e4 erityisen tutkitun aiheen viime\nvuosikymmenien aikana. Vastaavasti halogeenisidoksen luonteen parempi ymm\u00e4rrys,\nmuista heikoista vuorovaikutuksista eroavat ominaisuudet ja monimuotoiset sovellusalat\novat aiheuttaneet tutkijoiden mielenkiinnon her\u00e4\u00e4misen t\u00e4h\u00e4n ilmi\u00f6\u00f6n.\nKoordinaatioh\u00e4kkej\u00e4 k\u00e4sitell\u00e4\u00e4n t\u00e4ss\u00e4 tutkielmassa erilaisien koordinaation ohjaamaan\nitsej\u00e4rjestymiseen perustuvien valmistustekniikoiden kautta. Kustakin valmistustekniikasta\non esitetty perusperiaatteet koordinaatioh\u00e4kkien valmistukseen ja esimerkkej\u00e4\nvalmistetusta koordinaatioh\u00e4kist\u00e4. Halogeenisidoksesta taas k\u00e4sitell\u00e4\u00e4n sidoksen\nperusperiaatteet, edelleen kiistanalainen halogeenisidoksen luonne, esimerkkej\u00e4\nvuorovaikutukseen osallistuvista yhdisteist\u00e4 ja suhdetta muihin vastaaviin heikkoihin\nvuorovaikutuksiin. Lis\u00e4ksi k\u00e4sitell\u00e4\u00e4n koordinaatioh\u00e4kkien ja halogeenisidoksia sis\u00e4lt\u00e4vien\nyhdisteiden yleisi\u00e4 tutkimusmenetelmi\u00e4 ja sovelluksia, sek\u00e4 koordinaatioh\u00e4kkej\u00e4, joiden\nrakenteessa tai toiminnassa hy\u00f6dynnet\u00e4\u00e4n halogeenisidosta.\nTutkielman kokeellisessa osassa suoritettiin kompleksointireaktioita erilaisten\nsinkkisuolojen ja N-donoriligandien v\u00e4lill\u00e4 tavoitteena muodostaa koordinaatioh\u00e4kkej\u00e4\nkoordinaation ohjaaman itsej\u00e4rjestymisen avulla. Kahdella potentiaalisella\nligandimolekyylill\u00e4 suoritettiin kokeita aiemmin kirjallisuudessa mainittujen, niin sanottujen\nhalonium-koordinaatioh\u00e4kkien analogirakenteiden muodostamiseksi. Lis\u00e4ksi tarkasteltiin\nhalogeenisidosdonorien l\u00e4sn\u00e4olon vaikutusta itsej\u00e4rjestymisprosesseihin sek\u00e4 h\u00e4kkien\nmuodostuksen osalta, ett\u00e4 my\u00f6s vain pelkkien ligandien l\u00e4sn\u00e4 ollessa. Syntetisoiduista\nyhdisteist\u00e4 yksikider\u00f6ntgendiffraktometrialla karakterisoitiin yhteens\u00e4 nelj\u00e4 h\u00e4kkim\u00e4ist\u00e4\nrakennetta, nelj\u00e4 kompleksiyhdistett\u00e4, viisi ligandirakennetta, seitsem\u00e4n halogeenisidoksia\nsis\u00e4lt\u00e4nytt\u00e4 rakennetta ja kolme jaetun varautuneen protonin rakennetta. Lis\u00e4ksi kaikki\nty\u00f6ss\u00e4 syntetisoidut ligandit analysoitiin termoanalyyttisill\u00e4 menetelmill\u00e4.", "language": "fi", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted by Miia Hakanen (mihakane@jyu.fi) on 2020-06-22T11:37:15Z\nNo. of bitstreams: 0", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Made available in DSpace on 2020-06-22T11:37:15Z (GMT). No. of bitstreams: 0\n Previous issue date: 2020", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.format.extent", "value": "164", "language": "", "element": "format", "qualifier": "extent", "schema": "dc"}, {"key": "dc.format.mimetype", "value": "application/pdf", "language": null, "element": "format", "qualifier": "mimetype", "schema": "dc"}, {"key": "dc.language.iso", "value": "fin", "language": null, "element": "language", "qualifier": "iso", "schema": "dc"}, {"key": "dc.rights", "value": "In Copyright", "language": "en", "element": "rights", "qualifier": null, "schema": "dc"}, {"key": "dc.subject.other", "value": "halogeenisidos", "language": "", "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "koordinaatioh\u00e4kki", "language": "", "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "koordinaatiosidos", "language": "", "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.title", "value": "Koordinaatioh\u00e4kit ja halogeenisitoutuminen", "language": "", "element": "title", "qualifier": null, "schema": "dc"}, {"key": "dc.type", "value": "master thesis", "language": null, "element": "type", "qualifier": null, "schema": "dc"}, {"key": "dc.identifier.urn", "value": "URN:NBN:fi:jyu-202006224310", "language": "", "element": "identifier", "qualifier": "urn", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Pro gradu -tutkielma", "language": "fi", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Master\u2019s thesis", "language": "en", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Matemaattis-luonnontieteellinen tiedekunta", "language": "fi", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Faculty of Sciences", "language": "en", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Kemian laitos", "language": "fi", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Department of Chemistry", "language": "en", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "Jyv\u00e4skyl\u00e4n yliopisto", "language": "fi", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "University of Jyv\u00e4skyl\u00e4", "language": "en", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Ep\u00e4orgaaninen ja analyyttinen kemia", "language": "fi", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Inorganic and Analytical Chemistry", "language": "en", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "yvv.contractresearch.funding", "value": "0", "language": "", "element": "contractresearch", "qualifier": "funding", "schema": "yvv"}, {"key": "dc.type.coar", "value": "http://purl.org/coar/resource_type/c_bdcc", "language": null, "element": "type", "qualifier": "coar", "schema": "dc"}, {"key": "dc.rights.accesslevel", "value": "openAccess", "language": null, "element": "rights", "qualifier": "accesslevel", "schema": "dc"}, {"key": "dc.type.publication", "value": "masterThesis", "language": null, "element": "type", "qualifier": "publication", "schema": "dc"}, {"key": "dc.subject.oppiainekoodi", "value": "4031", "language": "", "element": "subject", "qualifier": "oppiainekoodi", "schema": "dc"}, {"key": "dc.subject.yso", "value": "kemia", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "jodi", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.format.content", "value": "fulltext", "language": null, "element": "format", "qualifier": "content", "schema": "dc"}, {"key": "dc.rights.url", "value": "https://rightsstatements.org/page/InC/1.0/", "language": null, "element": "rights", "qualifier": "url", "schema": "dc"}, {"key": "dc.type.okm", "value": "G2", "language": null, "element": "type", "qualifier": "okm", "schema": "dc"}]
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