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[{"key": "dc.contributor.advisor", "value": "Rissanen, Kari", "language": "", "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.author", "value": "Martikkala, Riku", "language": "", "element": "contributor", "qualifier": "author", "schema": "dc"}, {"key": "dc.date.accessioned", "value": "2018-12-13T07:48:02Z", "language": null, "element": "date", "qualifier": "accessioned", "schema": "dc"}, {"key": "dc.date.available", "value": "2018-12-13T07:48:02Z", "language": null, "element": "date", "qualifier": "available", "schema": "dc"}, {"key": "dc.date.issued", "value": "2018", "language": "", "element": "date", "qualifier": "issued", "schema": "dc"}, {"key": "dc.identifier.uri", "value": "https://jyx.jyu.fi/handle/123456789/60584", "language": null, "element": "identifier", "qualifier": "uri", "schema": "dc"}, {"key": "dc.description.abstract", "value": "Tutkielmassa k\u00e4sitell\u00e4\u00e4n kahta supramolekulaarisen sitoutumisen muotoa, vetysitoutumista\nja halogeenisitoutumista. Molemmista sitoutumismuodoista l\u00e4pi k\u00e4yd\u00e4\u00e4n ilmi\u00f6n\nhistoriallisen perustan pohjalta nykyaikainen m\u00e4\u00e4rittelm\u00e4 reunaehtoineen. Molemmat\nsitoutumismuodot ovat osittain s\u00e4hk\u00f6magneettisia ja nimens\u00e4 mukaisesti\nvetysitoutumisessa sidokseen osallistuu osittain positiivisen varauksen saanut vetyatomi ja\nsiihen elektrostaattisesti liittyv\u00e4 nukleofiilinen atomi. Vastaavasti halogeenisitoutuminen\non elektrofiilisen halogeenin ja nukleofiilisen atomin v\u00e4linen vuorovaikutus.\nVetysitoutumisen kuvaamiseen tutkielmassa vesimolekyyli\u00e4 k\u00e4ytet\u00e4\u00e4n p\u00e4\u00e4asiallisena\nesimerkkin\u00e4 sek\u00e4 ep\u00e4orgaanisissa ett\u00e4 biologisissa ymp\u00e4rist\u00f6iss\u00e4. Halogeenisidoksen osalta\nesitell\u00e4\u00e4n ilmi\u00f6n mahdollisia k\u00e4ytt\u00f6kohteita ja olemassaolevia ilmi\u00f6n esiintymismuotoja\nvetysitoutumisen tapaan ep\u00e4orgaanisessa ja orgaanisessa ymp\u00e4rist\u00f6ss\u00e4. Lopuksi verrataan\nmolempia sitoutumisen muotoja, sill\u00e4 vetysitoutuminen on yleisesti sidoksista lujuudeltaan\nvahvempi ja helpommin hallittavissa oleva vuorovaikutus.\nR\u00f6ntgenkristallografisessa tarkastelussa k\u00e4yd\u00e4\u00e4n l\u00e4pi molempien sitoutumismuotojen\nsidospituuksia ja -kulmia Cambridge Structural Database \u2013 kristallograafiseen tietokantaan\npohjautuvan tarkastelun avulla. Vetysitoutuminen on useimmissa tapauksissa vahvempi\nsidospituuksia verrattaessa van der Waals vuorovaikutuksiin, kun halogeenisitoutuminen on\nsidoskulmiltaan s\u00e4\u00e4nn\u00f6llisempi.", "language": "fi", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted by Paivi Vuorio (paelvuor@jyu.fi) on 2018-12-13T07:48:02Z\nNo. of bitstreams: 0", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Made available in DSpace on 2018-12-13T07:48:02Z (GMT). No. of bitstreams: 0\n Previous issue date: 2018", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.format.extent", "value": "55", "language": "", "element": "format", "qualifier": "extent", "schema": "dc"}, {"key": "dc.format.mimetype", "value": "application/pdf", "language": null, "element": "format", "qualifier": "mimetype", "schema": "dc"}, {"key": "dc.language.iso", "value": "fin", "language": null, "element": "language", "qualifier": "iso", "schema": "dc"}, {"key": "dc.rights", "value": "In Copyright", "language": "en", "element": "rights", "qualifier": null, "schema": "dc"}, {"key": "dc.subject.other", "value": "halogeenisidos", "language": "", "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.title", "value": "Vetysitoutumisen ja halogeenisitoutumisen ominaisuuksien vertailu ja r\u00f6ntgenkristallografinen tarkastelu", "language": "", "element": "title", "qualifier": null, "schema": "dc"}, {"key": "dc.type", "value": "master thesis", "language": null, "element": "type", "qualifier": null, "schema": "dc"}, {"key": "dc.identifier.urn", "value": "URN:NBN:fi:jyu-201812135097", "language": "", "element": "identifier", "qualifier": "urn", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Pro gradu -tutkielma", "language": "fi", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Master\u2019s thesis", "language": "en", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Matemaattis-luonnontieteellinen tiedekunta", "language": "fi", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Faculty of Sciences", "language": "en", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Kemian laitos", "language": "fi", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Department of Chemistry", "language": "en", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "Jyv\u00e4skyl\u00e4n yliopisto", "language": "fi", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "University of Jyv\u00e4skyl\u00e4", "language": "en", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Orgaaninen kemia", "language": "fi", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Organic Chemistry", "language": "en", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "yvv.contractresearch.funding", "value": "0", "language": "", "element": "contractresearch", "qualifier": "funding", "schema": "yvv"}, {"key": "dc.type.coar", "value": "http://purl.org/coar/resource_type/c_bdcc", "language": null, "element": "type", "qualifier": "coar", "schema": "dc"}, {"key": "dc.rights.accesslevel", "value": "openAccess", "language": null, "element": "rights", "qualifier": "accesslevel", "schema": "dc"}, {"key": "dc.type.publication", "value": "masterThesis", "language": null, "element": "type", "qualifier": "publication", "schema": "dc"}, {"key": "dc.subject.oppiainekoodi", "value": "4035", "language": "", "element": "subject", "qualifier": "oppiainekoodi", "schema": "dc"}, {"key": "dc.subject.yso", "value": "vetysidokset", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "halogeenit", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "vuorovaikutus", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "vety", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.format.content", "value": "fulltext", "language": null, "element": "format", "qualifier": "content", "schema": "dc"}, {"key": "dc.rights.url", "value": "https://rightsstatements.org/page/InC/1.0/", "language": null, "element": "rights", "qualifier": "url", "schema": "dc"}, {"key": "dc.type.okm", "value": "G2", "language": null, "element": "type", "qualifier": "okm", "schema": "dc"}]
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