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[{"key": "dc.contributor.advisor", "value": "Rissanen, Kari", "language": "", "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.author", "value": "Aalto, Jenna", "language": null, "element": "contributor", "qualifier": "author", "schema": "dc"}, {"key": "dc.date.accessioned", "value": "2017-11-27T10:23:38Z", "language": "", "element": "date", "qualifier": "accessioned", "schema": "dc"}, {"key": "dc.date.available", "value": "2017-11-27T10:23:38Z", "language": "", "element": "date", "qualifier": "available", "schema": "dc"}, {"key": "dc.date.issued", "value": "2017", "language": null, "element": "date", "qualifier": "issued", "schema": "dc"}, {"key": "dc.identifier.other", "value": "oai:jykdok.linneanet.fi:1801931", "language": null, "element": "identifier", "qualifier": "other", "schema": "dc"}, {"key": "dc.identifier.uri", "value": "https://jyx.jyu.fi/handle/123456789/56012", "language": "", "element": "identifier", "qualifier": "uri", "schema": "dc"}, {"key": "dc.description.abstract", "value": "T\u00e4m\u00e4n Pro gradu\u2013tutkielman ensimm\u00e4isess\u00e4 osassa perehdyt\u00e4\u00e4n kaliksi[4]resorsinareenien eli resorsinareenien monipuoliseen kemiaan, synteeseihin sek\u00e4 niiden sovelluksien ominaisuuksiin, kuten nestekiteiden muodostumiseen. Toisessa osassa k\u00e4sitell\u00e4\u00e4n bentsoksatsiinien kemiaa, niiden ominaisuuksia ja mahdollisuuksia uusien sovellusten kannalta, esimerkiksi teollisuudessa.\r\nKuppimaisen muodon johdosta resorsinareenit ovat hyvi\u00e4 is\u00e4nt\u00e4-molekyylej\u00e4 pienille poolisille orgaanisille molekyyleille sek\u00e4 kationeille. Resorsinareenit, jotka ovat syklisi\u00e4 tetrameerej\u00e4, syntetisoidaan happokatalysoidulla kondensaatioreaktiolla. Resorsinareeneilla on useita konformaatioita, joista vain osa on tutkimuksissa l\u00f6ydetty.\r\nBentsoksatsiinit sis\u00e4lt\u00e4v\u00e4t rakenteessaan oksatsiinirenkaan. Ne voivat olla monomeerisi\u00e4, polymeerin osina tai itse polymerisoitua. Polymerisaatio tapahtuu yleens\u00e4 ROP-polymerisaatiolla, Ring Opening Polymerization, l\u00e4mmitt\u00e4m\u00e4ll\u00e4 ja initiaattoria k\u00e4ytt\u00e4m\u00e4ll\u00e4. Bentsoksatsiinien johdannaisilla on paljon teollisuudessa haluttavia ja hy\u00f6dynnett\u00e4vi\u00e4 ominaisuuksia, kuten suuri lasisiirtym\u00e4l\u00e4mp\u00f6tila. Bentsoksatsiineja voidaan hyvin monipuolisesti r\u00e4\u00e4t\u00e4l\u00f6id\u00e4 eri tarkoituksiin sopiviksi, kuten elektroniikkaan tai erilaisiin pinnoitteisiin.", "language": "fi", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted using Plone Publishing form by Jenna Aalto (jenmaraa) on 2017-11-27 10:23:37.152034. Form: Pro gradu -lomake (https://kirjasto.jyu.fi/julkaisut/julkaisulomakkeet/pro-gradu-lomake). JyX data: [jyx_publishing-allowed (fi) =True]", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted by jyx lomake-julkaisija (jyx-julkaisija.group@korppi.jyu.fi) on 2017-11-27T10:23:38Z\r\nNo. of bitstreams: 2\r\nURN:NBN:fi:jyu-201711274383.pdf: 1241191 bytes, checksum: 129b60ca9ea5244b12c0db7f201b7411 (MD5)\r\nlicense.html: 4796 bytes, checksum: 789a8f5bf99d222716bbdf1e989bfb32 (MD5)", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Made available in DSpace on 2017-11-27T10:23:38Z (GMT). No. of bitstreams: 2\r\nURN:NBN:fi:jyu-201711274383.pdf: 1241191 bytes, checksum: 129b60ca9ea5244b12c0db7f201b7411 (MD5)\r\nlicense.html: 4796 bytes, checksum: 789a8f5bf99d222716bbdf1e989bfb32 (MD5)\r\n Previous issue date: 2017", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.format.extent", "value": "1 verkkoaineisto (66 sivua)", "language": null, "element": "format", "qualifier": "extent", "schema": "dc"}, {"key": "dc.format.mimetype", "value": "application/pdf", "language": null, "element": "format", "qualifier": "mimetype", "schema": "dc"}, {"key": "dc.language.iso", "value": "fin", "language": null, "element": "language", "qualifier": "iso", "schema": "dc"}, {"key": "dc.rights", "value": "In Copyright", "language": "en", "element": "rights", "qualifier": null, "schema": "dc"}, {"key": "dc.subject.other", "value": "resorsinareeni", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "bentsoksatsiini", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.title", "value": "Resorsinareenien ja bentsoksatsiinien kemia", "language": null, "element": "title", "qualifier": null, "schema": "dc"}, {"key": "dc.type", "value": "master thesis", "language": null, "element": "type", "qualifier": null, "schema": "dc"}, {"key": "dc.identifier.urn", "value": "URN:NBN:fi:jyu-201711274383", "language": null, "element": "identifier", "qualifier": "urn", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Pro gradu -tutkielma", "language": "fi", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Master\u2019s thesis", "language": "en", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Matemaattis-luonnontieteellinen tiedekunta", "language": "fi", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Faculty of Sciences", "language": "en", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Kemian laitos", "language": "fi", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Department of Chemistry", "language": "en", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "University of Jyv\u00e4skyl\u00e4", "language": "en", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "Jyv\u00e4skyl\u00e4n yliopisto", "language": "fi", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Orgaaninen kemia", "language": "fi", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Organic Chemistry", "language": "en", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.date.updated", "value": "2017-11-27T10:23:38Z", "language": "", "element": "date", "qualifier": "updated", "schema": "dc"}, {"key": "yvv.contractresearch.funding", "value": "0", "language": "", "element": "contractresearch", "qualifier": "funding", "schema": "yvv"}, {"key": "dc.type.coar", "value": "http://purl.org/coar/resource_type/c_bdcc", "language": null, "element": "type", "qualifier": "coar", "schema": "dc"}, {"key": "dc.rights.accesslevel", "value": "openAccess", "language": "fi", "element": "rights", "qualifier": "accesslevel", "schema": "dc"}, {"key": "dc.type.publication", "value": "masterThesis", "language": null, "element": "type", "qualifier": "publication", "schema": "dc"}, {"key": "dc.subject.oppiainekoodi", "value": "4035", "language": null, "element": "subject", "qualifier": "oppiainekoodi", "schema": "dc"}, {"key": "dc.format.content", "value": "fulltext", "language": null, "element": "format", "qualifier": "content", "schema": "dc"}, {"key": "dc.rights.url", "value": "https://rightsstatements.org/page/InC/1.0/", "language": null, "element": "rights", "qualifier": "url", "schema": "dc"}, {"key": "dc.type.okm", "value": "G2", "language": null, "element": "type", "qualifier": "okm", "schema": "dc"}]
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