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[{"key": "dc.contributor.advisor", "value": "V\u00e4is\u00e4nen, Ari", "language": "", "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.advisor", "value": "Per\u00e4m\u00e4ki, Siiri", "language": "", "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.author", "value": "Niskanen, Tuukka", "language": null, "element": "contributor", "qualifier": "author", "schema": "dc"}, {"key": "dc.date.accessioned", "value": "2017-09-12T11:30:59Z", "language": "", "element": "date", "qualifier": "accessioned", "schema": "dc"}, {"key": "dc.date.available", "value": "2017-09-12T11:30:59Z", "language": "", "element": "date", "qualifier": "available", "schema": "dc"}, {"key": "dc.date.issued", "value": "2017", "language": null, "element": "date", "qualifier": "issued", "schema": "dc"}, {"key": "dc.identifier.other", "value": "oai:jykdok.linneanet.fi:1723675", "language": null, "element": "identifier", "qualifier": "other", "schema": "dc"}, {"key": "dc.identifier.uri", "value": "https://jyx.jyu.fi/handle/123456789/55332", "language": "", "element": "identifier", "qualifier": "uri", "schema": "dc"}, {"key": "dc.description.abstract", "value": "T\u00e4ss\u00e4 tutkielmassa tarkasteltiin hiilen matriisivaikutuksia induktiivisesti kytketty\u00e4 plasmaa (ICP) hy\u00f6dynt\u00e4viss\u00e4 analyysimenetelmiss\u00e4. Kirjallisessa osassa on tarkasteltu erilaisia kiinteiden n\u00e4ytteiden esik\u00e4sittelymenetelmi\u00e4 kiinnitt\u00e4en huomiota j\u00e4\u00e4nn\u00f6shiilim\u00e4\u00e4riin. Lis\u00e4ksi l\u00e4pi k\u00e4yd\u00e4\u00e4n ICP-tekniikoiden teoriaa, laitteistoa ja h\u00e4iri\u00f6it\u00e4, painotuksen ollessa hiilen aiheuttamissa ongelmatekij\u00f6iss\u00e4. Kokeellisessa osassa tutkittiin onko hiilell\u00e4 merkitt\u00e4vi\u00e4 vaikutuksia muovien hivenaineille (As, Cd, Cr, Pb, Sb, Sn, Zn, S) sellaisissa pitoisuuksissa, joita j\u00e4\u00e4nn\u00f6shiilipitoisuudelta voidaan odottaa kiinteiden n\u00e4ytteiden esik\u00e4sittelyn j\u00e4lkeen. J\u00e4ljitellen sertifioituja muovimateriaaleja valmistettiin synteettiset n\u00e4ytteet, jotka sis\u00e4lsiv\u00e4t eri\u00e4vi\u00e4 m\u00e4\u00e4ri\u00e4 hiilitaustaa. Hiilitaustaisille n\u00e4ytteille etsittiin optimaaliset mittausolosuhteet induktiivisesti kytketty plasma optinen emissio spektroskopialla (ICP-OES), ja n\u00e4it\u00e4 olosuhteita hy\u00f6dynnettiin sertifioitujen vertailumateriaalien tarkasteluun. Hiilitaustaisia n\u00e4ytteit\u00e4 mitattiin sek\u00e4 ICP-OES:ll\u00e4 ett\u00e4 induktiivisesti kytketty plasma massaspektrometrialla (ICP-MS). Lis\u00e4ksi ICP-OES:ll\u00e4 tarkasteltiin mahdollisia hiilen ja helposti ionisoituvien alkuaineiden (EIE) yhteisvaikutuksia. Tuloksista havaittiin, ettei hiilell\u00e4 ole merkitt\u00e4vi\u00e4 vaikutuksia kyseisten alkuaineiden mittaamiseen n\u00e4iss\u00e4 plasmoissa ja j\u00e4\u00e4nn\u00f6shiilitasoa vastaavissa hiilipitoisuuksissa. Tinan emission havaittiin putoavan 50 % k\u00e4ytett\u00e4ess\u00e4 5000 mg/l hiilitaustaa sek\u00e4 200 mg/l EIE taustaa ICP-OES:ll\u00e4. Tulosten perusteella tarkasteltujen analyyttien analysointi voidaan tehd\u00e4 luotettavasti k\u00e4ytetty\u00e4 menetelm\u00e4\u00e4 hy\u00f6dynt\u00e4en.", "language": "fi", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.abstract", "value": "In this thesis the matrix effects of carbon in inductively coupled plasma (ICP) techniques were investigated. In the literature review different solid sample preparation methods were compared with special attention to their residual carbon amounts. In addition, ICP theory, equipment and interferences, especially those of carbon, were presented. In the experimental section of this work, matrix effects of carbon at residual amounts on trace elements of plastic materials (As, Cd, Cr, Pb, Sb, Sn, Zn, S) were evaluated. Synthetic samples with different carbon matrixes were prepared with certified plastic materials as a template. Optimal measuring parameters for carbon containing samples on inductively coupled plasma optical emission spectroscopy (ICP-OES) were determined. These conditions were further utilized in analysis of certified reference materials. Carbon matrix containing samples were measured with ICP-OES as well as inductively coupled plasma mass spectrometry (ICP-MS). In addition, possible cooperative action of carbon and easily-ionized-elements (EIE), were investigated with ICP-OES. It was concluded that residual amounts of carbon have no significant effect on the investigated elements in plasmas in question. The emission of tin in ICP-OES was observed to drop by 50 % in precence of 5000 mg/l of carbon and 200 mg/l of EIE matrix. According to these results the analysis of the investigated elements can be performed with confidence utlizing these evaluated methods.", "language": "en", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted using Plone Publishing form by Tuukka Niskanen (tutanisk) on 2017-09-12 11:30:58.514400. Form: Pro gradu -lomake (https://kirjasto.jyu.fi/julkaisut/julkaisulomakkeet/pro-gradu-lomake). JyX data: [jyx_publishing-allowed (fi) =True]", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted by jyx lomake-julkaisija (jyx-julkaisija.group@korppi.jyu.fi) on 2017-09-12T11:30:59Z\r\nNo. of bitstreams: 2\r\nURN:NBN:fi:jyu-201709123715.pdf: 4383729 bytes, checksum: d4f30b0d99f7a113b66686e87ed11fe8 (MD5)\r\nlicense.html: 4844 bytes, checksum: c9328b19a5a0f64511ddecb6830f174a (MD5)", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Made available in DSpace on 2017-09-12T11:30:59Z (GMT). No. of bitstreams: 2\r\nURN:NBN:fi:jyu-201709123715.pdf: 4383729 bytes, checksum: d4f30b0d99f7a113b66686e87ed11fe8 (MD5)\r\nlicense.html: 4844 bytes, checksum: c9328b19a5a0f64511ddecb6830f174a (MD5)\r\n Previous issue date: 2017", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.format.extent", "value": "1 verkkoaineisto (116 sivua)", "language": null, "element": "format", "qualifier": "extent", "schema": "dc"}, {"key": "dc.format.mimetype", "value": "application/pdf", "language": null, "element": "format", "qualifier": "mimetype", "schema": "dc"}, {"key": "dc.language.iso", "value": "fin", "language": null, "element": "language", "qualifier": "iso", "schema": "dc"}, {"key": "dc.rights", "value": "In Copyright", "language": "en", "element": "rights", "qualifier": null, "schema": "dc"}, {"key": "dc.subject.other", "value": "ICP-OES", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "ICP-MS", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.title", "value": "Hiilen taustavaikutukset muovien lis\u00e4aineille induktiivisesti kytketyss\u00e4 plasmassa", "language": null, "element": "title", "qualifier": null, "schema": "dc"}, {"key": "dc.type", "value": "master thesis", "language": null, "element": "type", "qualifier": null, "schema": "dc"}, {"key": "dc.identifier.urn", "value": "URN:NBN:fi:jyu-201709123715", "language": null, "element": "identifier", "qualifier": "urn", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Pro gradu -tutkielma", "language": "fi", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Master\u2019s thesis", "language": "en", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Matemaattis-luonnontieteellinen tiedekunta", "language": "fi", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Faculty of Sciences", "language": "en", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Kemian laitos", "language": "fi", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Department of Chemistry", "language": "en", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "University of Jyv\u00e4skyl\u00e4", "language": "en", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "Jyv\u00e4skyl\u00e4n yliopisto", "language": "fi", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Ep\u00e4orgaaninen ja analyyttinen kemia", "language": "fi", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Inorganic and Analytical Chemistry", "language": "en", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.date.updated", "value": "2017-09-12T11:30:59Z", "language": "", "element": "date", "qualifier": "updated", "schema": "dc"}, {"key": "yvv.contractresearch.funding", "value": "0", "language": "", "element": "contractresearch", "qualifier": "funding", "schema": "yvv"}, {"key": "dc.type.coar", "value": "http://purl.org/coar/resource_type/c_bdcc", "language": null, "element": "type", "qualifier": "coar", "schema": "dc"}, {"key": "dc.rights.accesslevel", "value": "openAccess", "language": "fi", "element": "rights", "qualifier": "accesslevel", "schema": "dc"}, {"key": "dc.type.publication", "value": "masterThesis", "language": null, "element": "type", "qualifier": "publication", "schema": "dc"}, {"key": "dc.subject.oppiainekoodi", "value": "4031", "language": null, "element": "subject", 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