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[{"key": "dc.contributor.advisor", "value": "Rissanen, Kari", "language": "", "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.advisor", "value": "Rodriguez, Laura", "language": "", "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.author", "value": "Svahn, Noora", "language": null, "element": "contributor", "qualifier": "author", "schema": "dc"}, {"key": "dc.date.accessioned", "value": "2017-08-17T16:44:26Z", "language": "", "element": "date", "qualifier": "accessioned", "schema": "dc"}, {"key": "dc.date.available", "value": "2017-08-17T16:44:26Z", "language": "", "element": "date", "qualifier": "available", "schema": "dc"}, {"key": "dc.date.issued", "value": "2017", "language": null, "element": "date", "qualifier": "issued", "schema": "dc"}, {"key": "dc.identifier.other", "value": "oai:jykdok.linneanet.fi:1719667", "language": null, "element": "identifier", "qualifier": "other", "schema": "dc"}, {"key": "dc.identifier.uri", "value": "https://jyx.jyu.fi/handle/123456789/55136", "language": "", "element": "identifier", "qualifier": "uri", "schema": "dc"}, {"key": "dc.description.abstract", "value": "L-glutamiinin ja polyglutamiinin molekyylintunnistuksessa k\u00e4ytettyjen uusien organometallikompleksien mielenkiintoiset luminesoivat ominaisuudet ovat per\u00e4isin 4-etynyylianiliiniligandista ja fosfaaniyksik\u00f6st\u00e4 sek\u00e4 molekyylien v\u00e4lisist\u00e4 Au\u22efAu vuorovaikutuksista. Heikkojen intermolekulaaristen vuorovaikutusten on havaittu johtavan kuitu- ja pallomaisten muotojen morfologisiin muutoksiin vierasmolekyylien l\u00e4sn\u00e4 ollessa. Muodostunut is\u00e4nt\u00e4-vieras -kompleksi tuottaa erilaisen emission vierasmolekyylist\u00e4 riippuen. Lis\u00e4ksi [Au(4-etynyylianiliini)(PTA)]:n itsej\u00e4rjest\u00e4ytymisen termodynaamisia funktioita tutkittiin eri pitoisuuksissa ja l\u00e4mp\u00f6tiloissa NMR mittausten avulla. N\u00e4m\u00e4 lineaariset kulta(I) -kompleksit j\u00e4rjest\u00e4ytyv\u00e4t pitkiksi kuiduiksi isodesmisen polymerisaatiomekanismin avulla, jonka on havaittu olevan entropian ajama riippumatta aikaisemmista tutkimuksista saman kaltaisilla komplekseilla.", "language": "fi", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.abstract", "value": "The study of new organometallic complexes possessing interesting luminescent properties that stem from the 4-ethynylaniline ligand with a contribution of phosphane unit and Au\u22efAu interactions, have been employed in molecular recognition of L-glutamine and polyglutamine. Weak intermolecular interactions have been found to result in fibrillary and spherical shapes of aggregates with different morphology in the presence of the guest molecules. The binding mode in the host-guest system shows different emission behaviour depending on the guest molecule. Furthermore, thermodynamic functions of the self-assembly of [Au(4ethynyl-aniline)(PTA)] was investigated through variable concentration and temperature NMR studies. The linear gold(I) complexes aggregate into long organized fibres via an isodesmic polymerisation mechanism and regardless of the previous studies with related complex the process has been observed to be entropically driven.", "language": "en", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted using Plone Publishing form by Noora Svahn (nokrsvah) on 2017-08-17 16:44:21.984644. Form: Pro gradu -lomake (https://kirjasto.jyu.fi/julkaisut/julkaisulomakkeet/pro-gradu-lomake). JyX data: [jyx_publishing-allowed (fi) =True]", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted by jyx lomake-julkaisija (jyx-julkaisija.group@korppi.jyu.fi) on 2017-08-17T16:44:26Z\r\nNo. of bitstreams: 2\r\nURN:NBN:fi:jyu-201708173513.pdf: 35534972 bytes, checksum: f4ed3995b1838069b589916f3d023529 (MD5)\r\nlicense.html: 4853 bytes, checksum: 5f6a7d288ffa600ea8690f7e066283ab (MD5)", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Made available in DSpace on 2017-08-17T16:44:26Z (GMT). No. of bitstreams: 2\r\nURN:NBN:fi:jyu-201708173513.pdf: 35534972 bytes, checksum: f4ed3995b1838069b589916f3d023529 (MD5)\r\nlicense.html: 4853 bytes, checksum: 5f6a7d288ffa600ea8690f7e066283ab (MD5)\r\n Previous issue date: 2017", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.format.extent", "value": "1 verkkoaineisto (53 sivua)", "language": null, "element": "format", "qualifier": "extent", "schema": "dc"}, {"key": "dc.format.mimetype", "value": "application/pdf", "language": null, "element": "format", "qualifier": "mimetype", "schema": "dc"}, {"key": "dc.language.iso", "value": "eng", "language": null, "element": "language", "qualifier": "iso", "schema": "dc"}, {"key": "dc.rights", "value": "In Copyright", "language": "en", "element": "rights", "qualifier": null, "schema": "dc"}, {"key": "dc.subject.other", "value": "Aggregation", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "Aurophilic interaction", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "Gold(I)", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "Luminescence", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "Molecular recognition", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "PEG", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.title", "value": "Supramolecular systems based on gold(I) derivatives : molecular recognition of L-glutamine and polyQ", "language": null, "element": "title", "qualifier": null, "schema": "dc"}, {"key": "dc.title.alternative", "value": "Molecular recognition of L-glutamine and polyQ", "language": null, "element": "title", 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