| fullrecord |
[{"key": "dc.contributor.author", "value": "Palom\u00e4ki, Markku", "language": null, "element": "contributor", "qualifier": "author", "schema": "dc"}, {"key": "dc.date.accessioned", "value": "2016-12-08T11:51:11Z", "language": "", "element": "date", "qualifier": "accessioned", "schema": "dc"}, {"key": "dc.date.available", "value": "2016-12-08T11:51:11Z", "language": "", "element": "date", "qualifier": "available", "schema": "dc"}, {"key": "dc.date.issued", "value": "2016", "language": null, "element": "date", "qualifier": "issued", "schema": "dc"}, {"key": "dc.identifier.other", "value": "oai:jykdok.linneanet.fi:1644755", "language": null, "element": "identifier", "qualifier": "other", "schema": "dc"}, {"key": "dc.identifier.uri", "value": "https://jyx.jyu.fi/handle/123456789/52231", "language": "", "element": "identifier", "qualifier": "uri", "schema": "dc"}, {"key": "dc.description.abstract", "value": "T\u00e4m\u00e4n pro gradu \u2013tutkielman kirjallinen osa k\u00e4sittelee entsyymien (CODH) katalysoimaa (k\u00e4\u00e4nteist\u00e4) hiilimonoksidin (CO) hapettumisreaktiota hiilidioksidiksi (CO_2). Reaktion aktiivipaikka (C-klusteri) sijaitsee anaerobisten mikrobien entsyymeiss\u00e4 (CODH). Aiempi (k\u00e4\u00e4nteisen) reaktion ja aktiivipaikan rakenteen tutkimus on hy\u00f6dynt\u00e4nyt sek\u00e4 kokeellisia ett\u00e4 laskennallisia menetelmi\u00e4. Kirjallisessa osassa k\u00e4yd\u00e4\u00e4n l\u00e4pi eri tutkimusmenetelmill\u00e4 saatuja tuloksia muun muassa reaktiomekanismista ja reaktion aktiivipaikan rakenteesta. Tutkimusten tuloksia on ollut tarkoitus hy\u00f6dynt\u00e4\u00e4 kemiallisissa synteeseiss\u00e4, joissa j\u00e4ljitell\u00e4\u00e4n C-klusterin rakennetta. Haasteena on ollut tuloksien tulkinta ja tutkimusdatan yhdist\u00e4minen yhten\u00e4iseksi kokonaisuudeksi.\r\nJoidenkin molekyylien tiedet\u00e4\u00e4n est\u00e4v\u00e4n entsyymin (CODH) katalyyttista aktiivisuutta. N\u00e4m\u00e4 molekyylit ovat rakenteellisesti ja elektronisesti analogisia suhteessa reaktion substraattehin (CO/CO_2). Inhibiittorit voivat valaista reaktion katalyyttista mekanismia. Kirjallisessa osassa keskityt\u00e4\u00e4n syanidin (CN^-) toimimiseen CO:n hapettumisen estoaineena.", "language": "fi", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted using Plone Publishing form by Markku Palom\u00e4ki (matapalo) on 2016-12-08 11:51:11.005874. Form: Pro gradu -lomake (https://kirjasto.jyu.fi/julkaisut/julkaisulomakkeet/pro-gradu-lomake). JyX data: [jyx_publishing-allowed (fi) =False]", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted by jyx lomake-julkaisija (jyx-julkaisija.group@korppi.jyu.fi) on 2016-12-08T11:51:11Z\r\nNo. of bitstreams: 2\r\nURN:NBN:fi:jyu-201612084998.pdf: 1842598 bytes, checksum: 49fbf76c7a2c3f954be04fa61f7502ef (MD5)\r\nlicense.html: 1184 bytes, checksum: 5218477423b9e0d2a3362f3b05b12435 (MD5)", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Made available in DSpace on 2016-12-08T11:51:11Z (GMT). No. of bitstreams: 2\r\nURN:NBN:fi:jyu-201612084998.pdf: 1842598 bytes, checksum: 49fbf76c7a2c3f954be04fa61f7502ef (MD5)\r\nlicense.html: 1184 bytes, checksum: 5218477423b9e0d2a3362f3b05b12435 (MD5)\r\n Previous issue date: 2016", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.format.extent", "value": "1 verkkoaineisto (68 sivua)", "language": null, "element": "format", "qualifier": "extent", "schema": "dc"}, {"key": "dc.format.mimetype", "value": "application/pdf", "language": null, "element": "format", "qualifier": "mimetype", "schema": "dc"}, {"key": "dc.language.iso", "value": "fin", "language": null, "element": "language", "qualifier": "iso", "schema": "dc"}, {"key": "dc.rights", "value": "In Copyright", "language": "en", "element": "rights", "qualifier": null, "schema": "dc"}, {"key": "dc.subject.other", "value": "syanidi", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.title", "value": "Entsyymien (CODH) katalysoima hiilimonoksidin (CO) hapettumisreaktio (CO/CO\u2082 ) ja syanidi (CN \u0304) hapettumisreaktion inhibiittorina", "language": null, "element": "title", "qualifier": null, "schema": "dc"}, {"key": "dc.type", "value": "master thesis", "language": null, "element": "type", "qualifier": null, "schema": "dc"}, {"key": "dc.identifier.urn", "value": "URN:NBN:fi:jyu-201612084998", "language": null, "element": "identifier", "qualifier": "urn", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Pro gradu -tutkielma", "language": "fi", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Master\u2019s thesis", "language": "en", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Matemaattis-luonnontieteellinen tiedekunta", "language": "fi", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Faculty of Sciences", "language": "en", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Kemian laitos", "language": "fi", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Department of Chemistry", "language": "en", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "University of Jyv\u00e4skyl\u00e4", "language": "en", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "Jyv\u00e4skyl\u00e4n yliopisto", "language": "fi", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Fysikaalinen kemia", "language": "fi", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Physical Chemistry", "language": "en", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.date.updated", "value": "2016-12-08T11:51:12Z", "language": "", "element": "date", "qualifier": "updated", "schema": "dc"}, {"key": "yvv.contractresearch.funding", "value": "0", "language": "", "element": "contractresearch", "qualifier": "funding", "schema": "yvv"}, {"key": "dc.type.coar", "value": "http://purl.org/coar/resource_type/c_bdcc", "language": null, "element": "type", "qualifier": "coar", "schema": "dc"}, {"key": "dc.rights.accesslevel", "value": "restrictedAccess", "language": "fi", "element": "rights", "qualifier": "accesslevel", "schema": "dc"}, {"key": "dc.type.publication", "value": "masterThesis", "language": null, "element": "type", "qualifier": "publication", "schema": "dc"}, {"key": "dc.subject.oppiainekoodi", "value": "4032", "language": null, "element": "subject", "qualifier": "oppiainekoodi", "schema": "dc"}, {"key": "dc.subject.yso", "value": "biokemia", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "katalyysi", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "entsyymit", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "inhibiittorit", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.format.content", "value": "fulltext", "language": null, "element": "format", "qualifier": "content", "schema": "dc"}, {"key": "dc.rights.url", "value": "https://rightsstatements.org/page/InC/1.0/", "language": null, "element": "rights", "qualifier": "url", "schema": "dc"}, {"key": "dc.type.okm", "value": "G2", "language": null, "element": "type", "qualifier": "okm", "schema": "dc"}]
|