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[{"key": "dc.contributor.advisor", "value": "Pihko, Petri", "language": null, "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.advisor", "value": "Leskinen, Mikko", "language": null, "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.author", "value": "Rahikainen, Hanna", "language": null, "element": "contributor", "qualifier": "author", "schema": "dc"}, {"key": "dc.date.accessioned", "value": "2016-09-30T10:06:10Z", "language": null, "element": "date", "qualifier": "accessioned", "schema": "dc"}, {"key": "dc.date.available", "value": "2016-09-30T10:06:10Z", "language": null, "element": "date", "qualifier": "available", "schema": "dc"}, {"key": "dc.date.issued", "value": "2016", "language": null, "element": "date", "qualifier": "issued", "schema": "dc"}, {"key": "dc.identifier.other", "value": "oai:jykdok.linneanet.fi:1575529", "language": null, "element": "identifier", "qualifier": "other", "schema": "dc"}, {"key": "dc.identifier.uri", "value": "https://jyx.jyu.fi/handle/123456789/51482", "language": null, "element": "identifier", "qualifier": "uri", "schema": "dc"}, {"key": "dc.description.abstract", "value": "Suzuki-Miyaura kytkent\u00e4 on yksi t\u00e4rkeist\u00e4 orgaanisen kemian ty\u00f6kaluista, jolla saadaan integroitua hiili-hiilisidoksia molekyyleihin. T\u00e4m\u00e4 palladiumkatalysoitu reaktio on kiinnostanut tutkijoita sen helppouden ja k\u00e4yt\u00e4nn\u00f6llisyyden takia jo muutaman vuosikymmenen ajan. Reaktiossa on mahdollista k\u00e4ytt\u00e4\u00e4 mm. homogeenisi\u00e4 katalyyttej\u00e4, eli katalyyttej\u00e4, jotka sekoittuvat reaktioseokseen eli ovat samassa faasissa (neste/neste) tai heterogeenisi\u00e4 katalyyttej\u00e4, jotka eiv\u00e4t sekoitu reaktioseokseen eli ovat eri faaseissa (neste/kiinte\u00e4). Homogeeniset Pd-katalyytit ovat olleet k\u00e4yt\u00f6ss\u00e4 pitk\u00e4\u00e4n mutta niiden k\u00e4ytt\u00f6\u00e4 varjostaa mm. palladiumj\u00e4\u00e4m\u00e4t reaktioseokseen ja katalyytin erottamisen vaikeus samasta faasista johtuen. Heterogeeninen Pd-katalyytti voisi ratkaista Pd-j\u00e4\u00e4mien ongelman helpon erotettavuutensa ansiosta, sill\u00e4 esim. hiilipinnalle kiinnitetty palladiumkatalyytti Pd/C voitaisiin yksinkertaisesti suodattaa reaktioseoksesta pois. Kierr\u00e4tett\u00e4v\u00e4 heterogeeninen katalyytti voisi my\u00f6s laskea prosessikustannuksia, kun uutta palladiumia ei tarvitsisi aina ostaa uutta katalyytti\u00e4 varten vaan vanhan palladiumin voisi kierr\u00e4tt\u00e4\u00e4. Pro gradu on rakenteeltaan kaksiosainen, josta ensimm\u00e4inen osa on kirjallisuuskatsaus heterogeenisesti katalysoituihin Suzuki-Miyaura -kytkent\u00f6ihin, keskittyen pyridiinipohjaisiin Pd/C-katalysoituihin reaktioihin. Kirjallisuusosuudessa k\u00e4yd\u00e4\u00e4n ensin l\u00e4pi p\u00e4\u00e4periaatteita ja k\u00e4sitteit\u00e4 Suzuki-Miyaura -reaktiosta, jonka j\u00e4lkeen keskityt\u00e4\u00e4n pyridiinien heterogeeniseen Suzuki-Miyaura \u2013kytkent\u00e4\u00e4n, erityisesti Pd/C-katalysoituna. Toinen osa on Fermion Oy:ll\u00e4 suoritettu kokeellinen osa, jossa tutkittiin homogeenisen katalyytin korvaamisen mahdollisuutta heterogeenisell\u00e4 katalyytill\u00e4 mm. erilaisten N-heterosyklien Suzuki-Miyaura -kytkenn\u00e4ss\u00e4.", "language": "fi", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted using Plone Publishing form by Hanna Rahikainen (haelanra) on 2016-09-30 10:06:08.714371. Form: Pro gradu -lomake (https://kirjasto.jyu.fi/julkaisut/julkaisulomakkeet/pro-gradu-lomake). JyX data: [jyx_publishing-allowed (fi) =True]", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted by jyx lomake-julkaisija (jyx-julkaisija.group@korppi.jyu.fi) on 2016-09-30T10:06:10Z\nNo. of bitstreams: 2\nURN:NBN:fi:jyu-201609304239.pdf: 16914925 bytes, checksum: dd4c64e9e89294145442407bb8373dbe (MD5)\nlicense.html: 4817 bytes, checksum: 470a02a990a3233fa0e6ccb60c64d18f (MD5)", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Made available in DSpace on 2016-09-30T10:06:10Z (GMT). No. of bitstreams: 2\nURN:NBN:fi:jyu-201609304239.pdf: 16914925 bytes, checksum: dd4c64e9e89294145442407bb8373dbe (MD5)\nlicense.html: 4817 bytes, checksum: 470a02a990a3233fa0e6ccb60c64d18f (MD5)\n Previous issue date: 2016", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.format.extent", "value": "1 verkkoaineisto (108 sivua)", "language": null, "element": "format", "qualifier": "extent", "schema": "dc"}, {"key": "dc.format.mimetype", "value": "application/pdf", "language": null, "element": "format", "qualifier": "mimetype", "schema": "dc"}, {"key": "dc.language.iso", "value": "fin", "language": null, "element": "language", "qualifier": "iso", "schema": "dc"}, {"key": "dc.rights", "value": "In Copyright", "language": "en", "element": "rights", "qualifier": null, "schema": "dc"}, {"key": "dc.subject.other", "value": "heterogeeninen katalyytti", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.title", "value": "Heterogeeniset katalyytit Suzuki-Miyaura -kytkenn\u00e4ss\u00e4", "language": null, "element": "title", "qualifier": null, "schema": "dc"}, {"key": "dc.type", "value": "master thesis", "language": null, "element": "type", "qualifier": null, "schema": "dc"}, {"key": "dc.identifier.urn", "value": "URN:NBN:fi:jyu-201609304239", "language": null, "element": "identifier", "qualifier": "urn", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Pro gradu -tutkielma", "language": "fi", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Master\u2019s thesis", "language": "en", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Matemaattis-luonnontieteellinen tiedekunta", "language": "fi", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Faculty of Sciences", "language": "en", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Kemian laitos", "language": "fi", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Department of Chemistry", "language": "en", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "University of Jyv\u00e4skyl\u00e4", "language": "en", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "Jyv\u00e4skyl\u00e4n yliopisto", "language": "fi", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Orgaaninen kemia", "language": "fi", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Organic Chemistry", "language": "en", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.date.updated", "value": "2016-09-30T10:06:11Z", "language": null, "element": "date", "qualifier": "updated", "schema": "dc"}, {"key": "yvv.contractresearch.collaborator", "value": "business", "language": null, "element": "contractresearch", "qualifier": "collaborator", "schema": "yvv"}, {"key": "yvv.contractresearch.funding", "value": "12000", "language": null, "element": "contractresearch", "qualifier": "funding", "schema": "yvv"}, {"key": "yvv.contractresearch.initiative", "value": "student", "language": null, "element": "contractresearch", "qualifier": "initiative", "schema": "yvv"}, {"key": "dc.type.coar", "value": "http://purl.org/coar/resource_type/c_bdcc", "language": null, "element": "type", "qualifier": "coar", "schema": "dc"}, {"key": "dc.rights.accesslevel", "value": "openAccess", "language": "fi", "element": "rights", "qualifier": "accesslevel", "schema": "dc"}, {"key": "dc.type.publication", "value": "masterThesis", "language": null, "element": "type", "qualifier": "publication", "schema": "dc"}, {"key": "dc.subject.oppiainekoodi", "value": "4035", "language": null, "element": "subject", "qualifier": "oppiainekoodi", "schema": "dc"}, {"key": "dc.subject.yso", "value": "palladium", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "Suzuki-Miyaura - kytkent\u00e4", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.format.content", "value": "fulltext", "language": null, "element": "format", "qualifier": "content", "schema": "dc"}, {"key": "dc.rights.url", "value": "https://rightsstatements.org/page/InC/1.0/", "language": null, "element": "rights", "qualifier": "url", "schema": "dc"}, {"key": "dc.type.okm", "value": "G2", "language": null, "element": "type", "qualifier": "okm", "schema": "dc"}]
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