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[{"key": "dc.contributor.author", "value": "Sahamies, Joona", "language": null, "element": "contributor", "qualifier": "author", "schema": "dc"}, {"key": "dc.date.accessioned", "value": "2016-03-15T12:03:27Z", "language": "", "element": "date", "qualifier": "accessioned", "schema": "dc"}, {"key": "dc.date.available", "value": "2016-03-15T12:03:27Z", "language": "", "element": "date", "qualifier": "available", "schema": "dc"}, {"key": "dc.date.issued", "value": "2016", "language": null, "element": "date", "qualifier": "issued", "schema": "dc"}, {"key": "dc.identifier.other", "value": "oai:jykdok.linneanet.fi:1524429", "language": null, "element": "identifier", "qualifier": "other", "schema": "dc"}, {"key": "dc.identifier.uri", "value": "https://jyx.jyu.fi/handle/123456789/49052", "language": "", "element": "identifier", "qualifier": "uri", "schema": "dc"}, {"key": "dc.description.abstract", "value": "Pro gradu -tutkielmani keskittyy metallofiiliseen vuorovaikutukseen ylip\u00e4\u00e4t\u00e4ns\u00e4 ja etenkin metallofiiliseen vuorovaikutukseen metalliatomiketjuissa. Metallopolymeerien ja niiden er\u00e4\u00e4n alaluokan, laajennettujen metalliatomiketjujen (EMAC), m\u00e4\u00e4ritelm\u00e4t esitell\u00e4\u00e4n sek\u00e4 niiden k\u00e4ytt\u00f6kohteista ja ominaisuuksista on esimerkkej\u00e4. Metallofiilinen vuorovaikutus metalliatomien attraktiivista vuorovaikutusta, jossa metallien elektronikuori on t\u00e4ynn\u00e4 (s2 tai d10) tai k\u00e4ytt\u00e4ytyy, kuten se olisi t\u00e4ynn\u00e4 (d8). Se on voimakkuudeltaan korkeintaan vetysidoksen luokkaa. T\u00e4t\u00e4 metallofiilist\u00e4 vuorovaikutusta esiintyy my\u00f6s samanmerkkisesti varattujen metalli-ionien v\u00e4lill\u00e4. Metallofiilinen vuorovaikutus koostuu p\u00e4\u00e4osin dispersiivisest\u00e4 vuorovaikutuksesta, mutta se koostuu my\u00f6s osin ionisesta vuorovaikutuksesta ja vaihtovuorovaikutuksesta. Suhteellisuusteoreettiset vaikutukset voimistavat sitoutumista.\r\n\r\nAtomien v\u00e4lisen et\u00e4isyyden kasvaessa vuorovaikutus muuttuu kovalenttisest\u00e4 van der Waals vuorovaikutukseksi, mutta miss\u00e4 t\u00e4m\u00e4 raja on, ei ole selv\u00e4. T\u00e4m\u00e4n takia erilaisiin taulukoituihin s\u00e4teisiin on suhtauduttava hyvin varovaisesti ja kriittisesti, sill\u00e4 monet tekij\u00e4t vaikuttavat s\u00e4teisiin ja atomit eiv\u00e4t ole py\u00f6reit\u00e4. Jos atomien v\u00e4linen et\u00e4isyys on pienempi kuin van der Waals s\u00e4teiden summa, kyseess\u00e4 ei v\u00e4ltt\u00e4m\u00e4tt\u00e4 ole puoleensavet\u00e4v\u00e4 vuorovaikutus, jos esim. molekyylin j\u00e4ykkyys pakottaa tietyt atomit l\u00e4helle toisiaan, ne aiheuttavat hylkiv\u00e4n vuorovaikutuksen puoleensavet\u00e4v\u00e4n sijasta. Pikseli- ja sidospolkumenetelm\u00e4t on esitetty parempana vaihtoehtona atomien ja molekyylien v\u00e4lisien vuorovaikutuksien tutkimiseen.\r\n\r\nKokeellinen osa keskittyi homo- ja etenkin hetero-EMAC:ien valmistamiseen ja kiteytt\u00e4miseen k\u00e4ytt\u00e4en ryhm\u00e4n 11 metalleita ryhm\u00e4n ulkopuolisten metallien kanssa ja pyridiini-4(1H)-tionia ambidentaattina ligandina. Yksi heterometallinen EMAC saatiin valmistettua. Se koostuu polymeerisest\u00e4 [Cu2(s-pyH4]n2n+:sta n:ll\u00e4 [ZnCl4]2\u2212-vasta-anioneita. Metalliatomiketju on pseudolineaarinen ja kuparin koordinaatiogeometria on v\u00e4\u00e4ntynyt tetraedri. Cu\u2219\u2219\u2219Cu-et\u00e4isyydet ovat 2,6241(6) ja 2,6283(6) \u00c5 ja Cu\u2219\u2219\u2219Cu\u2219\u2219\u2219Cu-kulmat ovat 156,667(18)\u00b0 ja 157,424(19)\u00b0.", "language": "fi", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.abstract", "value": "This thesis concerns about metallophilic interaction in general and especially in metal atomic strings. The theoretical part of this thesis presents the definition, properties and applications of metallopolymers and its subclass extended metal atom chains (EMACs). The concept of metallophilic interaction is discussed. Unclarity between an interaction and a bond is also dissected. Critical view to tabulated values of van der Waals and covalent radii are discussed and emphasized that atoms are not spheres. More advances models like pixel and bond path methods to describe interaction are presented. Classification of EMACs with literature examples is also presented.\r\nHomo- and especially heterometallic EMACs were attempted to crystallize in the experimental part using group 11 metal salts, pyridine 4(1H) thione (s-pyH) as ambidentate ligand and other metal salts. One heterometallic EMAC, 1, was been able to crystallize. It was [Cu2(s-pyH)4]n2n+ with n [ZnCl4]2\u2212 counter anions. The metal atom string is pseudolinear. Coordination geometry of copper was twisted tetrahedral. The copper\u2013copper distances were 2.6241(6) and 2.6283(6) \u00c5. Cu\u2013Cu\u2013Cu angles are 156.667(18)\u00b0 and 157.424(19)\u00b0.", "language": "en", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted using Plone Publishing form by Joona Sahamies (joomiksa) on 2016-03-15 12:03:26.388625. Form: Pro gradu -lomake (https://kirjasto.jyu.fi/julkaisut/julkaisulomakkeet/pro-gradu-lomake). JyX data: [jyx_publishing-allowed (fi) =True]", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted by jyx lomake-julkaisija (jyx-julkaisija.group@korppi.jyu.fi) on 2016-03-15T12:03:27Z\r\nNo. of bitstreams: 2\r\nURN:NBN:fi:jyu-201603151846.pdf: 4158619 bytes, checksum: 55db0acafb09317bb95c340109b7a300 (MD5)\r\nlicense.html: 4802 bytes, checksum: 533f4a10c3d306e220bd1803d70de799 (MD5)", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Made available in DSpace on 2016-03-15T12:03:27Z (GMT). No. of bitstreams: 2\r\nURN:NBN:fi:jyu-201603151846.pdf: 4158619 bytes, checksum: 55db0acafb09317bb95c340109b7a300 (MD5)\r\nlicense.html: 4802 bytes, checksum: 533f4a10c3d306e220bd1803d70de799 (MD5)\r\n Previous issue date: 2016", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.format.extent", "value": "1 verkkoaineisto (174 sivua)", "language": null, "element": "format", "qualifier": "extent", "schema": "dc"}, {"key": "dc.format.mimetype", "value": "application/pdf", "language": null, "element": "format", "qualifier": "mimetype", "schema": "dc"}, {"key": "dc.language.iso", "value": "eng", "language": null, "element": "language", "qualifier": "iso", "schema": "dc"}, {"key": "dc.rights", "value": "In Copyright", "language": "en", "element": "rights", "qualifier": null, "schema": "dc"}, {"key": "dc.subject.other", "value": "metallofiilinen vuorovaikutus", "language": "", "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "metallophilic interactions", "language": "", "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "atomien v\u00e4liset et\u00e4isyydet", "language": "", "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.subject.other", "value": "interatomic distances", "language": "", "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.title", "value": "Homo- and heterometallic metal atomic strings", "language": null, "element": "title", "qualifier": null, "schema": "dc"}, {"key": "dc.type", "value": "master thesis", "language": null, "element": "type", "qualifier": null, "schema": "dc"}, {"key": "dc.identifier.urn", "value": "URN:NBN:fi:jyu-201603151846", "language": null, "element": "identifier", "qualifier": "urn", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Pro gradu -tutkielma", "language": "fi", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Master\u2019s thesis", "language": "en", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Matemaattis-luonnontieteellinen tiedekunta", "language": "fi", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Faculty of Sciences", "language": "en", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Kemian laitos", "language": "fi", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Department of Chemistry", "language": "en", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "University of Jyv\u00e4skyl\u00e4", "language": "en", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "Jyv\u00e4skyl\u00e4n yliopisto", "language": "fi", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Ep\u00e4orgaaninen ja analyyttinen kemia", "language": "fi", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Inorganic and Analytical Chemistry", "language": "en", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.date.updated", "value": "2016-03-15T12:03:27Z", "language": "", "element": "date", "qualifier": "updated", "schema": "dc"}, {"key": "yvv.contractresearch.funding", "value": "0", "language": "", "element": "contractresearch", "qualifier": "funding", "schema": "yvv"}, {"key": "dc.type.coar", "value": "http://purl.org/coar/resource_type/c_bdcc", "language": null, "element": "type", "qualifier": "coar", "schema": "dc"}, {"key": "dc.rights.accesslevel", "value": "openAccess", "language": "fi", "element": "rights", "qualifier": "accesslevel", "schema": "dc"}, {"key": "dc.type.publication", "value": "masterThesis", "language": null, "element": "type", "qualifier": "publication", "schema": "dc"}, {"key": "dc.subject.oppiainekoodi", "value": "4031", "language": null, "element": "subject", "qualifier": "oppiainekoodi", "schema": "dc"}, {"key": "dc.subject.yso", "value": "metallit", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "atomit", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.format.content", "value": "fulltext", "language": null, "element": "format", "qualifier": "content", "schema": "dc"}, {"key": "dc.rights.url", "value": "https://rightsstatements.org/page/InC/1.0/", "language": null, "element": "rights", "qualifier": "url", "schema": "dc"}, {"key": "dc.type.okm", "value": "G2", "language": null, "element": "type", "qualifier": "okm", "schema": "dc"}]
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