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[{"key": "dc.contributor.advisor", "value": "Nissinen, Maija", "language": "", "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.advisor", "value": "Helttunen, Kaisa", "language": "", "element": "contributor", "qualifier": "advisor", "schema": "dc"}, {"key": "dc.contributor.author", "value": "Virtanen, Tiina", "language": null, "element": "contributor", "qualifier": "author", "schema": "dc"}, {"key": "dc.date.accessioned", "value": "2015-03-03T16:01:52Z", "language": "", "element": "date", "qualifier": "accessioned", "schema": "dc"}, {"key": "dc.date.available", "value": "2015-03-03T16:01:52Z", "language": "", "element": "date", "qualifier": "available", "schema": "dc"}, {"key": "dc.date.issued", "value": "2014", "language": null, "element": "date", "qualifier": "issued", "schema": "dc"}, {"key": "dc.identifier.other", "value": "oai:jykdok.linneanet.fi:1467557", "language": null, "element": "identifier", "qualifier": "other", "schema": "dc"}, {"key": "dc.identifier.uri", "value": "https://jyx.jyu.fi/handle/123456789/45436", "language": "", "element": "identifier", "qualifier": "uri", "schema": "dc"}, {"key": "dc.description.abstract", "value": "T\u00e4m\u00e4n pro gradu -tutkielman aiheena on grafeenioksidin kiehtova maailma. Tutkielman tavoitteena oli tehd\u00e4 kattava kirjallisuuskatsaus grafeenioksidin funktionalisoinnista. Tutkielmassa k\u00e4yd\u00e4\u00e4n l\u00e4pi grafeenioksidin t\u00e4rkeimm\u00e4t rakenteelliset piirteet, fysikaalis-kemialliset ominaisuudet, kemialliset funktionalisointimenetelm\u00e4t sek\u00e4 sovelluskohteet bioteknologiassa ja muualla. Ominaisuuksien tarkastelussa on kiinnitetty erityist\u00e4 huomiota hapetusasteen merkitykseen sek\u00e4 grafeenioksidin fluoresenssiin. Kemiallisten funktionalisointimenetelmien osiossa keskityt\u00e4\u00e4n l\u00e4hinn\u00e4 epoksidi- ja hydroksyyliryhmien\r\nfunktionalisointireaktioihin. Karboksyylihapporyhmien reaktioista on annettu my\u00f6s muutamia esimerkkej\u00e4. Sovelluskohteiden osiossa esitell\u00e4\u00e4n puolestaan grafeenioksidin ja metallinanopartikkelien hybridimateriaaleihin perustuvia tunnistusalustoja sek\u00e4 sensoreita. Viimeinen poikkitieteellisempi osio keskittyy grafeenioksidin mielenkiintoisiin sovelluskohteisiin bioteknologian alalla.\r\n\r\nErikoisty\u00f6 k\u00e4sittelee puolestaan tiolisuojattujen hopeananopartikkelien synteesi\u00e4. Ty\u00f6n p\u00e4\u00e4asiallisena tavoitteena on ollut (PPh4)4[Ag44(SC6H4F)30]-, Cs4Ag44(p-MBA)30- ja Na4Ag44(SC6H4F)30-partikkelien valmistaminen kirjallisuudessa esitettyjen synteesien mukaisesti. Partikkelien ominaisuuksista on ker\u00e4tty my\u00f6s hieman kokeellista lis\u00e4tietoa. Hopeananopartikkelien lis\u00e4ksi valmistettiin pentyyliresorsinareeni-bis-tiakruunujen v\u00e4lituotteita sek\u00e4 etyyliresorsinareeni-bis-tiakruunu.", "language": "fi", "element": "description", "qualifier": "abstract", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted using Plone Publishing form by Tiina Virtanen (tiirvirt) on 2015-03-03 16:01:12.086300. Form: Pro gradu -lomake (https://kirjasto.jyu.fi/julkaisut/julkaisulomakkeet/pro-gradu-lomake). JyX data: [jyx_publishing-allowed (fi) =True]", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Submitted by jyx lomake-julkaisija (jyx-julkaisija@noreply.fi) on 2015-03-03T16:01:52Z\r\nNo. of bitstreams: 2\r\nURN:NBN:fi:jyu-201503031410.pdf: 85942704 bytes, checksum: 9d800c47c78d93cd6a17cad4fa42ddfd (MD5)\r\nlicense.html: 4823 bytes, checksum: 979d91c5b7bb755a82fbf4ae9c4d094c (MD5)", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.description.provenance", "value": "Made available in DSpace on 2015-03-03T16:01:52Z (GMT). No. of bitstreams: 2\r\nURN:NBN:fi:jyu-201503031410.pdf: 85942704 bytes, checksum: 9d800c47c78d93cd6a17cad4fa42ddfd (MD5)\r\nlicense.html: 4823 bytes, checksum: 979d91c5b7bb755a82fbf4ae9c4d094c (MD5)\r\n Previous issue date: 2014", "language": "en", "element": "description", "qualifier": "provenance", "schema": "dc"}, {"key": "dc.format.extent", "value": "1 verkkoaineisto (200 sivua)", "language": null, "element": "format", "qualifier": "extent", "schema": "dc"}, {"key": "dc.format.mimetype", "value": "application/pdf", "language": null, "element": "format", "qualifier": "mimetype", "schema": "dc"}, {"key": "dc.language.iso", "value": "fin", "language": null, "element": "language", "qualifier": "iso", "schema": "dc"}, {"key": "dc.rights", "value": "In Copyright", "language": "en", "element": "rights", "qualifier": null, "schema": "dc"}, {"key": "dc.subject.other", "value": "grafeenioksidi", "language": null, "element": "subject", "qualifier": "other", "schema": "dc"}, {"key": "dc.title", "value": "Grafeenioksidin funktionalisointi", "language": null, "element": "title", "qualifier": null, "schema": "dc"}, {"key": "dc.type", "value": "master thesis", "language": null, "element": "type", "qualifier": null, "schema": "dc"}, {"key": "dc.identifier.urn", "value": "URN:NBN:fi:jyu-201503031410", "language": null, "element": "identifier", "qualifier": "urn", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Pro gradu -tutkielma", "language": "fi", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.type.ontasot", "value": "Master\u2019s thesis", "language": "en", "element": "type", "qualifier": "ontasot", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Matemaattis-luonnontieteellinen tiedekunta", "language": "fi", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.faculty", "value": "Faculty of Sciences", "language": "en", "element": "contributor", "qualifier": "faculty", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Kemian laitos", "language": "fi", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.department", "value": "Department of Chemistry", "language": "en", "element": "contributor", "qualifier": "department", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "University of Jyv\u00e4skyl\u00e4", "language": "en", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.contributor.organization", "value": "Jyv\u00e4skyl\u00e4n yliopisto", "language": "fi", "element": "contributor", "qualifier": "organization", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Orgaaninen kemia", "language": "fi", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.subject.discipline", "value": "Organic Chemistry", "language": "en", "element": "subject", "qualifier": "discipline", "schema": "dc"}, {"key": "dc.date.updated", "value": "2015-03-03T16:01:52Z", "language": "", "element": "date", "qualifier": "updated", "schema": "dc"}, {"key": "yvv.contractresearch.funding", "value": "0", "language": "", "element": "contractresearch", "qualifier": "funding", "schema": "yvv"}, {"key": "dc.type.coar", "value": "http://purl.org/coar/resource_type/c_bdcc", "language": null, "element": "type", "qualifier": "coar", "schema": "dc"}, {"key": "dc.rights.accesslevel", "value": "openAccess", "language": "fi", "element": "rights", "qualifier": "accesslevel", "schema": "dc"}, {"key": "dc.type.publication", "value": "masterThesis", "language": null, "element": "type", "qualifier": "publication", "schema": "dc"}, {"key": "dc.subject.oppiainekoodi", "value": "4035", "language": null, "element": "subject", "qualifier": "oppiainekoodi", "schema": "dc"}, {"key": "dc.subject.yso", "value": "biotekniikka", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "nanohiukkaset", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.subject.yso", "value": "grafeeni", "language": null, "element": "subject", "qualifier": "yso", "schema": "dc"}, {"key": "dc.format.content", "value": "fulltext", "language": null, "element": "format", "qualifier": "content", "schema": "dc"}, {"key": "dc.rights.url", "value": "https://rightsstatements.org/page/InC/1.0/", "language": null, "element": "rights", "qualifier": "url", "schema": "dc"}, {"key": "dc.type.okm", "value": "G2", "language": null, "element": "type", "qualifier": "okm", "schema": "dc"}]
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